Beyond 50 years of marriage each anniversary year does not have a symbol or material associated with it, rather every 5 years is celebrated with the exception of 65 years of marriage which has no traditional symbol associated with the year although Star Sapphire is often quoted.
Although there is a symbol for every 5th year up until 100 years of marriage we have yet to see anyone achieve an anniversary over 90 years although given people are now living longer we feel this is only a matter of time before this occurs. Wikipedia maintain a list of couples who have had the longest marriage together.
55th Wedding anniversary
The traditional fifty-fifth wedding anniversary gift has a theme of 55th; an alternative traditional fifty-fifth wedding anniversary gift can be themed with Emerald. The modern fifty-fifth wedding anniversary gift has a theme of Emerald. The gemstone fifty-fifth wedding anniversary gift has a theme of Alexandrite.
60th Wedding anniversary gifts
The modern sixtieth wedding anniversary gift has a theme of Diamonds. The gemstone sixtieth wedding anniversary gift has a theme of Diamonds.
65th Wedding anniversary gifts
The sixty-fifth wedding anniversary gift has a theme of Star Sapphire.
70th Wedding anniversary gifts
The modern seventieth wedding anniversary gift has a theme of Platinum.
75th Wedding anniversary gifts
The traditional seventy-fifth wedding anniversary gift has a theme of Diamonds. The modern seventy-fifth wedding anniversary gift has a theme of Diamonds.
80th Wedding anniversary gifts
The eightieth wedding anniversary gift has a theme of Pearls; an alternative modern eightieth wedding anniversary gift can be themed with Diamonds. Oak has also been mentioned although no reference source can be found for this theme.
85th Wedding anniversary gifts
The eight-fifth wedding anniversary gift has a theme of Sapphire; an alternative modern eight fifth wedding anniversary gift can be themed with Diamonds.
90th Wedding anniversary gifts
The ninetieth wedding anniversary gift has a theme of Diamonds; an alternative modern ninetieth wedding anniversary gift can be themed with Emerald.
95th Wedding anniversary gifts
The ninety-fifth wedding anniversary gift has a theme of Ruby; an alternative modern ninety fifth wedding anniversary gift can be themed with Diamonds.
100th Wedding anniversary gifts
The one hundredth wedding anniversary gift has a theme of Ten Carat Diamond.